段征教授——郑州大学化学与分子工程学院博士生导师

郑大考研网

段征, 男, 1973年生, 药学博士，教授，河南省高等学校青年骨干教师，河南省教育厅学术技术带头人，中法有机磷功能材料实验室副主任（郑州大学，CNRS-Université de Rennes 1）。

1995年郑州大学化学系本科毕业，1998年河南师范大学化学系，河南省化学研究所硕士毕业。2002年日本北海道大学药学部药学博士。2002-2003年日本北海道大学触媒研究中心 博士后。2004-2005年美国加州大学河滨分校化学系博士后。2005年郑州大学化学系教授，2009年中法有机磷功能材料实验室副主任（郑州大学，CNRS-Université de Rennes 1）。2009.10-11法国雷恩一大访问教授（CNRS-Université de Rennes 1）。

主要研究领域：有机磷化学，有机合成方法学、金属有机化学。

联系方式：郑州市科学大道号郑州大学化学系

郑州市 450001

Email:     duanzheng@zzu.edu.cn

主要发表文章

1.        Huaiqiu Wang, Chuan Li, Dingjin Geng, Hui Chen, Zheng Duan,* François Mathey*

A New Versatile Route for the Conversion of Phospholes into Phosphinines

Chem. Eur.J. 2010, published online.

2.        Congbao Huang, Hui Liu, Jianzhen Zhang, Zheng Duan* , François Mathey*

    Dimethyl Acetylenedicarboxylate and Phospholes: A Variety of Reaction Pathways

    Eur.J.Org.Chem., 2010, published online.

3.        Francois Mathey*, 段征*

低配位有机磷化学研究概况

中国科学：化学， 2010,40, 888-892.

(Francois Mathey*, Zheng Duan*, A concise review of low coordinated organophosphorus compounds, Sci. China Ser.B 2010,40, 888-892. invited paper)

4.        Rongqiang Tian, Hui Liu, Zheng Duan,* Francois Mathey*

    The Abnormal Hydrolysis of 7-Phosphanorbornenium Salts: A Case of

Phosphonium-Phosphenium Equivalence

J. Am. Chem.Soc., 2009, 131, 16008-16009.

5.        Rongqiang Tian, Zheng Duan,* Xiaoxu Zhou, Dingjin Geng, Yangjie Wu and Francois Mathey*         

Phosphole-N-phenylmaleimide [4+2] cycloadducts as synthetic equivalents of nucleophilic phosphinidenes

Chem.Commun., 2009, 2589-2590.

6.        Gerui Ren，Jinli Zhang，Zheng Duan，Mengjun Cui，Yangjie Wu*

A Simple and Economic Synthesis of Propargylamines by CuI-Catalyzed Three-Component Coupling Reaction with Succinic Acid as Additive.

Aust. J. Chem. 2009, 62, 75-81.

7.        Zhong Xian Li, Zheng Duan *, Yang Jie Wu *

FeCl3 catalyzed diarylmethanes formations

Chin. Chem. Lett., 2009, 20, 511-513.

8.        Zheng Duan*, Jianzhen Zhang, Rongqiang Tian, Liuying Bai, and Francois Mathey*

    Reinvestigation of the Reactions of 1-Phenyl-3,4-dimethylphosphole with Dimethyl Acetylenedicarboxylate

Organometallics 2008, 27, 5169–5171

9.        Zhongxian Li, Zheng Duan*, Huaiqiu Wang, Rongqiang Tian, Qianrui Zhu and Yangjie Wu*

    An Efficient Iodine-Catalyzed Benzylation Reaction of 1,3-Dicarbonyl Compounds

Synlett 2008, 4, 2535–2539.

10.    Yi-nan Cheng, Zheng Duan,* Liujian Yu, Zhongxian Li, Yu Zhu, Yangjie Wu*

    Palladium-Catalyzed Three-Component Arylcyanation of Internal Alkynes with Aryl Bromides and K4[Fe(CN)6]

    Organic Lett., 2008, 10, 901-904.

11.    Zhongxian Li, Zheng Duan*, Jianxun Kang, Huaiqiu Wang, Liujian Yu, Yangjie Wu*

A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3

Tetrahedron, 2008, 64, 1924-1930

12.    Zheng Duan, Magali Clochard, Bruno Donnadieu, Francüois Mathey,* and Fook S. Tham

Synthesis and X-ray Crystal Structure of a P-Confused Carbaporphyrinoid

Organometallics, 2007, 26, 3617-3620.

13.    Zheng Duan*, Xuejie Xuan, Yangjie Wu*

FeCl3 catalyzed addition of activated methylenes to styrene derivatives under air

Tetrahedron Lett., 2007, 48, 5157–5159

14.    Yi-nan Cheng, Zheng Duan,* Ting Li, Yangjie Wu*

Palladium catalyzed Cyanation of Aryl Bromides with Potassium Hexacynoferrate(II)

Lett. Org. Chem., 2007, 4, 352-356.

15.    Yi-nan Cheng, Zheng Duan,* Ting Li, Yangjie Wu*

    Cyanation of Aryl Chlorides with Potassium Hexacyanoferrate(II) Catalyzed

by Cyclopalladated Ferrocenylimine Tricyclohexylphosphine Complexes

Synlett 2007, 4, 543–546

16.    Zheng Duan,* Xuejie Xuan, Ting Li, Chenfei Yang and Yangjie Wu*

Cerium(IV) ammonium nitrate (CAN) catalyzed aza-Michael addition of amines to α,β-unsaturated electrophiles

Tetrahedron Lett., 2006, 47, 5433–5436

17.    Ning Ma, Zheng Duan ，Yangjie Wu*

DAB-Cy as an inexpensive and effective ligand for palladium-catalyzed homocoupling reaction of aryl halides
J.Organomet. Chem., 2006，691，5697-5700

18.    Zheng Duan, Takahiro Nishimoto, Masamichi Ogasawara, and Tamotsu Takahashi

Diallene Formation by Copper(I)-Mediated Reaction of Zirconacyclopentanes with Propargyl Halides

Synthesis. 2005, 2055-2060

19.    Zheng Duan, Bruno Donnadieu, Francois Mathey

    An access to original 3, 3-bis(phospholyl)lactones

    J.Organometallic.Chem., 2005, 690, 450-453

20.    Takashi Seki, Yoshinori Noguchi, Duan Zheng, Wen-hua Sun and Tamotsu Takahashi

Reaction of zirconacyclopentadienes with electrophiles such as benzaldehyde, methacrylate and1-bromo-2-butyne after treatment with RLi

      Tetrahedron Lett., 2004, 45, 9041-9043.

21.    Zheng Duan, Kiyohiko Nakajima and Tamotsu Takahashi.

Naphthalene formation by allylation of zirconaindenes in the ZnX2-Pd(PPh3)4 system.

Chem.Commun., 2001, 1672-1673.

22.    Zheng Duan, Wen-Hua Sun, Yuanhong Liu and Tamotsu Takahashi.

Formation of cyclopentadiene derivatives by reaction of zirconacyclopentadienes with 1, 1-dihalo compounds.

Tetrahedron Let t, 2000, 41, 7471-7474.

23.    Tamotsu Takahashi, Wen-Hua Sun, Zheng Duan and Baojian Shen.        

Preparation of benzocycloheptene derivatives from zirconacyclopentadienes.

Organic Lett., 2000, 2, 1197-1199.

专利

1.         段征，吴养洁， 程绎南，李挺，二茂铁亚胺环钯配合物催化下芳基腈类衍生物的合成方法，申请号：200610048481.9，专利号：ZL200610048481.9

2.        段征， 吴养洁， 李中贤，三芳基甲烷及衍生物的合成方法，申请号：200710054325.8，专利号：ZL 200710054325.8